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New York Fashion Week kicked off with a major bang.

As they do each year, Hollywood's finest gathered to honor those who’ve raised awareness on the HIV/AIDS epidemic at the annual amfAR New York Gala, which was held this year at Cipriani Wall Street.

PHOTOS: Stars Don Daring Dresses for 2014 amfAR Gala

"Since 1998, the amfAR New York Gala has become one of New York City’s most successful and high-profile AIDS benefit events," says the organization, which has been advocating for AIDS research since its founding in 1985. "The Gala consistently attracts — and salutes — some of the biggest names in entertainment, fashion, art, and AIDS advocacy."

"To date, the amfAR New York Gala has raised more than $15 million," the organization adds.

PHOTOS: Sharon Stone Goes to the Dark Side at amfAR Gala

And at such a glamorous black-tie affair, the stars in attendance rose to the occasion in breathtaking, stunning ensembles. From old Hollywood glamour to more modern styles featuring dangerous slits and daring V-neck cuts, it was difficult to keep our jaws off the floor.

Check out the 20 amfAR all-stars you won’t be able to look away from:








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Jourdan Dunn



Age 25, model.







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Padma Lakshmi



Age 45, model and cookbook author.







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Hannah Davis



Age 25, model.







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Chanel Iman



Age 25, model.







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Adriana Lima



Age 34, Victoria's Secret Angel.







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Sara Sampaio



Age 24, Victoria's Secret Angel







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Petra Nemcova



Age 36, model.







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Carol Alt



Age 55, model.







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Jemima Kirke



Age 30, actress.







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Charli XCX



Age 23, singer.







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Lauren Cohan



Age 34, actress.











Heidi Klum



Age 42, model.







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Karlie Kloss



Age 23, model.







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Paris and Nicky Hilton (L-R)



Ages 34 and 32, heiresses.







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Hailey Baldwin



Age 19, model.







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Diane Kruger



Age 39, actress.







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Emily Ratajkowski



Age 24, model.







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Blake Lively



Age 28, actress.







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Izabel Goulart



Age 31, model.